Synthesis of Tris(4-Methoxyphenyl)Phenylsilane Using Phenylsilane and 4-Iodo Anisole Catalyzed by Palladium Complex

Authors

Aldes Lesbani, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Ogan Ilir 30662, Sumatera Selatan, IndonesiaFollow
Risfidian Mohadi, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Ogan Ilir 30662, Sumatera Selatan, Indonesia
Eliza Eliza, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Ogan Ilir 30662, Sumatera Selatan, Indonesia
Mardiyanto Mardiyanto, Department of Pharmacy, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Ogan Ilir 30662, Sumatera Selatan, Indonesia

Abstract

Sintesis Tris(4-Metoksifenil)Fenilsilan Menggunakan Fenilsilan dan 4-Iodida Anisol dengan Katalis Senyawa Kompleks Paladium. Sintesis tris(4-metoksifenil)fenilsilan melalui reaksi kopling antara fenilsilan dan 4-iodida anisol menggunakan senyawa paladium tersier tributilfosfin sebagai katalis telah dilakukan berdasarkan penentuan senyawa basa, pelarut, dan waktu reaksi kopling. Hasil penelitian menunjukkan bahwa senyawa tris(4-metoksifenil)fenilsilan dapat disintesis menghasilkan persentase produk maksimum pada penggunaan senyawa 1,4-diazabisiko[2,2,2]oktan (DABCO) sebagai basa, tetrahidrofuran sebagai pelarut, dan waktu reaksi kopling selama 5 hari. Persentase tertinggi produk senyawa tris(4-metoksifenil)fenilsilan adalah 35%.

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Recommended Citation

Lesbani, Aldes; Mohadi, Risfidian; Eliza, Eliza; and Mardiyanto, Mardiyanto (2014) "Synthesis of Tris(4-Methoxyphenyl)Phenylsilane Using Phenylsilane and 4-Iodo Anisole Catalyzed by Palladium Complex," Makara Journal of Science: Vol. 18: Iss. 1, Article 13.
DOI: 10.7454/mss.v18i1.3051
Available at: https://scholarhub.ui.ac.id/science/vol18/iss1/13