•  
  •  
 

Abstract

Chromium compounds are widely used in modern industry. Many of these compounds are dumped into the surrounding environment. Membrane technology is more efficient and effective than conventional methods for waste treatment. The research objective was to make a membrane separation process that can be applied to Cr(VI). Membranes were made from chitosan and silica rice husks. Variations of chitosan and silica rice husk used (g) are 2:1 (A1), 2:2 (A2), 3:1 (B1), and 3:2 (B2). The membrane was made by using an inverted phase technique. Results of SEM characterization of membranes showed that B2 has the largest pores at 2.58 μm. The FTIR characterization results indicate the presence of crosslinking between chitosan with silica rice husk with the appearance of Si-O adsorption band at wavelength 1122- 980/cm. A1 membrane, with the smallest pore size has the greatest rejection value towards Cr(VI) which is 70%. The result of this research showed that the composite membrane of silica rice husk was effective enough to adsorb metal Cr(VI) with an average adsorption capacity of 1665.85 mg/g.

References

[1] G. Gosh, P.K. Bhattacharya, Chem. Eng. J. 119 (2006) 45. [2] J. Wu, H. Zhang, P.J. He, Q. Yao, L.M. Shao, J. Hazard. Mater. 176 (2010) 697. [3] H. Gao, Y. Liu, G. Zeng,W. Xu, T. Li, W. Xia, J. Hazard. Mater. 150 (2008) 446. [4] P.L. Hariani, N. Hidayat, M.J. Oktaria, J. Penelitian Sains 12.2C.(2009) 1 (in Indonesia). [5] M. Lindu. J. Teknologi Lingkungan 4 (2008) 4 (in Indonesia). [6] A.L. Putro, D. Prasetyo, Akta kimindo 3 (2007) 33. [7] Meriatna, Thesis, Universitas Sumatera Utara, Medan, 2008 (in Indonesia). [8] X.F. Zeng, E. Ruckenstein, Ind. Eng. Chem. Res. 35/11 (1996) 4169. [9] E. Handayani, Tesis, Sekolah Pascasarjana Institut Pertanian Bogor, Bogor, 2009 (in Indonesia). [10] J. Liu, X. Chen, Z. Shao, P. Zhou, J. Appl. Polym. Sci. 90 (2003) 1108. [11] M. Kabsch-Korbutowicz, Mater. Sci.-Poland 26 (2008) 2. [12] A.L. Lim, R. Bai, J. Membrane Sci. 216 (2003) 279. [13] A. Tor, T. Buyukerkek, Y. Cengeloglu, M. Ersoz, Desalination 171 (2004) 233. [14] P.M. Devaprasath, J.S. Solomon, B.V. Thomas, J. Appl. Sci. Environ. Sanitation 2/3 (2007) 77. [15] Y. Vijaya, M.V. Subbaiah, A.S. Reddy, J.A. Priya, A. Krishnaiah, Indian J. Phys. Chem. 5 (2010) 22. [16] E. Malkoc, Y. Nuhouglu, Chem. Eng. Process. 46 (2007) 1020

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.