•  
  •  
 

Abstract

The substitution of Ti atoms by Al atoms in TiN lattice sites to form (Ti1-xAlx)N is clearly demonstrated by the coatings which were deposited on steel substrate and using plasma CVD technique. The presence of Al atoms in TiN lattice site is shown by means of XRD and EDX techniques: lattice parameters decreasing of TiN as the fraction of Al increases (XRD) and precipitation of hexagonal AlN phase (XRD) as the fraction of Al exceeding 0.8 (EDX). The hardness of these coating are just around 30 GPa, which is beyond the values reported in literatures.

Bahasa Abstract

Substitusi Atom Ti dengan Al dalam kristal TiN untuk membentuk paduan (Ti1-xAlx)N sangat jelas diperagakan dari lapisan tipis yang dideposisi di atas substrat stainless steel dengan menggunakan teknik plasma CVD. Adanya atom Al dalam kristal TiN ditunjukkan dengan XRD dan EDX: penurunan konstanta kisi TiN sesuai dengan kenaikan fraksi Al (XRD) dan presipitasi fase hexagonal AlN (XRD) ketika fraksi Al melewati 0,8 (EDX). Kekerasan lapisan tipis ini hanya sekitar 30 GPa, yang melebihi hasil-hasil yang ada dalam literatur.

References

O. Knotek, M. Böhmer, T. Leyendecker, J. Vac. Sci. Technol., A4 (1986) 2695.

O. Knotek, M. Böhmer, T. Leyendecker, J. Vac. Sci. Technol., A5 (1987) 2173.

P. Eh. Hovsepian, D. B. Lewis, W. –D. Münz, Surf. Coat. Technol., 133-134 (2000) 66.

C. Jarms, H. –R. Stock, P. Mayr, Surf. Coat. Technol. 108-109 (1998) 206.

S. H. Lee, H.J. Ryoo, J.J. Lee. J. Vac. Sci. Technol. A 12 (4), (1994) 1602.

K. Moto, PhD thesis, Technical University Munich, Germany, 2001.

K. Moto, X. Xiauo, D. S. Patil, S. Veprek, Seminar: NATO SfP-Project No.:972379. Brunn, Czech Republic, 4-5 October 2001.

S. Anderbouhr, E. Blanquet, V. Gettha, C. Bernard. Proc. of 11th Europ. Conf. CVD, Paris, (1997) 285.

J. Patcheider, Li Shizhi, Stan Veprek. Plasma Chem. and Plasma Process. 16 (1996) 431.

A. Leonhardt, K. Bartsch, I. Endler. Surf. Coat. Technol. 76-77 (1995) 225.

T. Ikeda, H. Satoh. Thin Solid Films, 195 (1991) 99.

S. Shimada, M. Yoshimatsu. Thin Solid Films 370 (2000) 146.

R. Prange, R. Cremer, D. Neuschütz. Surf. Coat. Technol. 133-134 (2000) 208.

Share

COinS
 
 

To view the content in your browser, please download Adobe Reader or, alternately,
you may Download the file to your hard drive.

NOTE: The latest versions of Adobe Reader do not support viewing PDF files within Firefox on Mac OS and if you are using a modern (Intel) Mac, there is no official plugin for viewing PDF files within the browser window.