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Abstract

Workers in oil and gas production units are at risk of exposure to chemical hazards. One of the ingredients in petroleum is volatile organic compounds (VOC), with examples of ingredients known for their toxicity being benzene, toluene and xylene. This study aims to assess health risks related to exposure to benzene, toluene and xylene of oil refinery workers at PT. X. This study will analyze personal exposure to inhalation routes from benzene, toluene and xylene chemicals using the Chemical Health Risk Assessment (CHRA) method from the Department of Safety and Health, Malaysia. The study results showed that the risk level from benzene was very high, while the risk level from toluene and xylene was at a moderate level. The highest exposure to benzene, toluene and xylene is in distillation units. Based on the results of the study, appropriate controls are needed to overcome exposure to benzene, toluene and xylene. One of the controls that can be done is to improve the ventilation system and tighten the use of personal protective equipment.

References

ACGIH (2021a) Benzene. Available at: https://www.acgih.org/benzene-notice-of-intended-change/.

ACGIH (2021b) Toluene. Available at: https://www.acgih.org/toluene/.

ACGIH (2021c) Xylene All Isomers. Available at: https://www.acgih.org/xylene-all-isomers/.

AIHA (2022) IHStat AIHA. Available at: https://www.aiha.org/public-resources/consumer-resources/apps-and-tools-resource-center/aiha-risk-assessment-tools#:~=IHSTATTM%20is%20an%20Excel,intended%20to%20accompany%20this%20tool

AIOH (2014) Occupational Hygiene Monitoring & Compliance Strategies. Available at: https://www.aioh.org.au/product/monitoring-pdf/

Aitani, A.M. (2004) ‘Oil Refining and Products’, Encyclopedia of Energy, pp. 714–729.

ATSDR (2002) Toxicological Profile for Benzene, ATSDR’s Toxicological Profiles. doi:10.1201/9781420061888_ch38.

ATSDR (2013) Toxicological Profile for Xylene. Available at: http://dx.doi.org/10.1155/2013/286524.

ATSDR (2016) Toxicology Profile for Toluene. Agency for Toxic Substances and Disease Registry. Available at: https://www.atsdr.cdc.gov/ToxProfiles/tp56-c10.pdf

ATSDR (2021) Xylenes, Agency for Toxic Substance and Disease Registry. Available at: https://www.atsdr.cdc.gov/toxprofiles/tp124.pdf

Banaszkiewicz, K., Marcinkowski, T. and Pasiecznik, I. (2022) ‘Fly Ash as an Infredient in the Contaminated Soil Stabilization Process’, Energies, 15(2).

Canadian Centre for Occupational Health and Safety (2020) Hazard and Risk - General. Available at: https://www.ccohs.ca/oshanswers/hsprograms/hazard/hazard_risk.html.

Canadian Centre for Occupational Health and Safety (2023) How Workplace Chemical Enter the Body. Available at: https://www.ccohs.ca/oshanswers/chemicals/how_chem.html.

Capleton, A.C. and Levy, L.S. (2005) ‘An overview of occupational benzene exposures and occupational exposure limits in Europe and North America’, 154, pp. 43–53. doi:10.1016/j.cbi.2005.03.007.

CDC (2023) Hierarchy of Controls. The National Institute for Occupational Safety and Health. Available at: https://www.cdc.gov/niosh/topics/hierarchy/default.html#:~=Engineering%20controls%20reduce%20or%20prevent,barriers%2C%20ventilation%2C%20and%20more

Chaiklieng, S. (2021) ‘Risk assessment of workers exposure to BTEX and hazardous area classification at gasoline stations’, PLoS ONE, 16(4), pp. 1–11. doi:10.1371/journal.pone.0249913.

Clark, C.R. et al. (2013) ‘A GHS-consistent approach to health hazard classification of petroleum substances, a class of UVCB substances’, Regulatory Toxicology and Pharmacology, 67(3), pp. 409–420. doi: https://doi.org/10.1016/j.yrtph.2013.08.020.

Department of Health New York State (2013) What You Know Can Help You - An Introduction to Toxic Substances. Available at: https://www.health.ny.gov/environmental/chemicals/toxic_substances.htm.

DOSH (2018) A Manual of Recommended Practice on Assessment of The Health Risks Arising from The Use of Chemicals Hazardous to Health at The Workplace. 3rd edn. Department of Occupational Safety and Health Malaysia.

Eaton, D.L. and Gilbert, S.G. (2013) ‘Principles of Toxicology’, in Toxicology The Basic Science of Poisons.

Federal Subsidiary Legislation (2000) Occupational Safety and Health (Use and Standards of Exposure of Chemicals Hazardous to Health) Regulations 2000. Available at: http://www.dosh.gov.my

Gallo, M.A. (2013) ‘History and Scope of Toxicology’, in Toxicology The Basic Science of Poisons.

Ghavamabadi, L.I. et al. (2022) ‘Assessing the effect of BTEX on blood and spirometry parameters staff in a petroleum refinery’, Front Public Health, 10.

Globally Harmonized System of Classification and Labelling of Chemicals (GHS) 10th Edition (2023).

De Graaff, R. et al. (2012) REACH - Analytical characterisation of petroleum UVCB substances, CONCAWE Reports.

Hansson, S.O. (2004) ‘Philosophical Perspectives on Risk’, Techné: Research in Philosophy & Technology, 8(1), pp. 10–35.

Hashemi, F. et al. (2021) ‘BTEX exposure of pregnant women and associations with pro-inflammatory cytokines (IL-6 and TNF-α)’, Air Qual Atmos Health, 15, pp. 707–719.

Health Safety Executive UK (2017) COSHH essentials : Controlling exposure to chemicals - a simple control banding approach.

Heibati, B. et al. (2017) ‘BTEX exposure assessment and quantitative risk assessment among petroleum product distributors’, Ecotoxicology and Environmental Safety, 144, pp. 445–449. doi:10.1016/j.ecoenv.2017.06.055.

Hoseini, L.K. and Yengejeh, R.J. (2022) ‘Health Risk Assessment of Volatile Organic Compounds ( VOCs ) in a Refinery in The Southwest of Iran Using SQRA Method’, Front Public Health [Preprint].

Hosseini, S.A. et al. (2023) ‘Assessment of health risk and burden of disease induced by exposure to benzene, toluene, ethylbenzene, and xylene in the outdoor air in Tehran, Iran’, 30, pp. 75989–76001. Available at: https://doi.org/10.1007/s11356-023-27889-z.

IARC (2018) Benzene. Lyon: International Agency for Research on Cancer. Available at: https://gco.iarc.fr/today/data/factsheets/cancers/2-Benzen.pdf

ILO (2004) What is Toxicology. Geneva: International Labour Organization. Available at: https://www.ilo.org/safework/info/publications/WCMS_107632/lang--en/index.htm

Imawati, P.F. (2021) Kajian Risiko Kesehatan Terkait Pajanan Bahaya Kimia Benzene, Toluene, dan Xylene di Dua Unit Pengolahan Minyak dan Gas Tahun 2017-2020. Universitas Indonesia.

International Labour Organization (2019) Safety and Health at the Heart of the Future of Work: Building on 100 Years of Experience. Available at: https://www.ilo.org

Jalilian, S. et al. (2022) Health Risk Assessment of Occupational Exposure of Refinery Unit Site Workers to BTEX in an Oil Refinery Company, J Health Sci Surveillance Sys.

Kementerian ESDM (2023) ‘Statistik Pertambangan Minyak dan Gas Bumi’, 34.

Kementerian ESDM (2024) Siaran Pers Kementerian ESDM No. 28.Pers/04/SJI/2024 tentang Konsumsi Listrik masyarakat Meningkat, Tahun 2023 Capai 1.285 kWh/Kapita.

Kesmodel, U.S. (2018) ‘Cross-sectional studies – what are they good for?’, Acta Obstetricia et Gynecologica Scandinavica, 97(4), pp. 388–393. doi:10.1111/aogs.13331.

Kirkeleit, J. (2007) Benzene exposure and hematological effects among offshore workers exposed to crude oil.

Kurniawidjaja, L.M. et al. (2021) Konsep Dasar Toksikologi Industri.

Macdonald, W. (2005) ‘A hierarchy of risk control measures for prevention of work-related musculoskeletal disorders’, International Ergonomics Conference, pp. 48–57.

National Center for Biotechnology Information (2024a) Pubchem Compound Summary for Benzene, Pubchem.

National Center for Biotechnology Information (2024b) Pubchem Compound Summary for Toluene, Pubchem.

National Center for Biotechnology Information (2024c) Pubchem Compound Summary for Xylene, Pubchem.

NIOSH (2019a) ‘NIOSH Pocket Guide to Chemical Hazards Benzene’. Available at: https://www.cdc.gov/niosh/npg/npgd0049.html.

NIOSH (2019b) NIOSH Pocket Guide to Chemical Hazards Toluene. Cincinnati, OH: National Institute for Occupational Safety and Health. Available at: https://www.cdc.gov/niosh/npg/npgd0426.html

NIOSH (2019c) NIOSH Pocket Guide to Chemical Hazards Xylene. Available at: https://www.cdc.gov/niosh/npg/npgd0668.html.

NIOSH (2020) Chemical Hazard, The National Institute for Occupational Safety and Health (NIOSH).

Nurhasnah (2021) Studi Pustaka Naratif : Gambaran Metode Penilaian Risiko Kesehatan Terkait Pajanan Bahaya Kimia. Available at: http://lib.fkm.ui.ac.id/detail?id=135007&lokasi=lokal#horizontalTab5.

Occupational Safety and Health Division (2005) A Semi-Quantitative Method to Assess Occupational Exposure to Harmful Chemical, Singapore: Ministry of Manpower. Ministry of Manpower Singapura.

OSHA (2021a) Benzene. Available at: https://www.osha.gov/chemicaldata/491.

OSHA (2021b) Xylene. Available at: https://www.osha.gov/chemicaldata/228.

OSHA (2022) Toluene, Occupational Safety and Health Administration. Available at: https://www.osha.gov/chemicaldata/89.

Peraturan Menteri Ketenagakerjaan Republik Indonesia (2018) Peraturan Menteri Ketenagakerjaan No. 50 Tahun 2018 tentang Nilai Ambang Batas (NAB) Bahan Kimia Berbahaya. Jakarta: Kementerian Ketenagakerjaan Republik Indonesia.

Peraturan Presiden Republik Indonesia Nomor 7 Tahun 2019 tentang Penyakit Akibat Kerja. (2019).

Permenaker (2018) Peraturan Menteri Ketenagakerjaan RI No. 5 Tahun 2018, Peraturan Menteri Ketenagakerjaan Republik Indonesia No. 5 Tahun 2018.

Plog, B. and Quinland, P. (2002) Fundamentals of Industrial Hygiene. 5th edn, Braunwald’s Heart Disease, 10/e. 5th edn. Edited by P. Quinland. National Safety Council. Available at: http://dx.doi.org/10.1016/B978-1-4557-5134-1.00001-9.

Pryor, P. (2019) ‘OHS Body of Knowledge’. Available at: https://www.ohsbok.org.au

Ridderseth, H. et al. (2022) ‘Occupational Benzene Exposure in the Norwegian Offshore Petroleum Industry , 2002 – 2018’, XX(Xx), pp. 895–906.

Robinson, L. (2019) ‘Human Health Risk Assessment’, in A Practical Guide to Toxicology and Human Health Risk Assessment. 1st edn.

Spellman, F. (2017) Industrial Hygiene Simplified: A Guide to Anticipation, Recognition, Evaluation and Control of Workplace Hazard. 2nd edn. Maryland: Bernan Press.

Susanto, A. et al. (2022) ‘Komparasi Penilaian Risiko Kesehatan Bahan Kimia: Metode CHRA Dan SQRA’, IAKMI Jurnal Kesehatan Masyarakat Indonesia, 3(1), pp. 1–12. doi:10.46366/ijkmi.3.1.1-12.

Tian, F. et al. (2018) ‘Qualitative and quantitative differences between common occupational health risk assessment models in typical industries’, Journal of Occupational Health, 60(5), pp. 337–347. doi:10.1539/joh.2018-0039-OA.

Tse, S.W. and Lai, G. (2002) ‘A review of COSHH essentials’, Process Safety and Environmental Protection: Transactions of the Institution of Chemical Engineers, Part B, 80(4), pp. 177–180. doi:10.1205/095758202320439128.

U.S. Energy Information Administration (2023) What countries are the top producers and consumers of oil? Available at: https://www.eia.gov/tools/faqs/

U.S. EPA (2012) Benzene. Washington, DC: U.S. Environmental Protection Agency. Available at: https://www.epa.gov

U.S. EPA (2023) Volatile Organic Compounds’ Impact on Indoor Air Quality. Available at: https://www.epa.gov/indoor-air-quality-iaq/volatile-organic-compounds-impact-indoor-air-quality.

Wang, S.M. et al. (2013) ‘Developing a semi-quantitative occupational risk prediction model for chemical exposures and its application to a national chemical exposure databank’, International Journal of Environmental Research and Public Health, 10(8), pp. 3157–3171. doi:10.3390/ijerph10083157.

Wang, T.S., Song, B., Sun, Q.H., Lin, Y.X., SUN, Y., et al. (2021) ‘Occupational Health Risk Assessment of Benzene, Toluene, and Xylene in Shanghai’, Biomedical and Environmental Sciences, 34(4), pp. 290–298. doi:10.3967/bes2021.038.

Wang, T.S., Song, B., Sun, Q.H., Lin, Y.X., Su, Y., et al. (2021) ‘Occupational Health Risk Assessment of Benzene, Toluene, and Xylene in Shanghai’, Biomedical and Environmental Sciences, 34(4), pp. 290–298. doi:10.3967/bes2021.038.

Weisel, C.P. (2010) ‘Benzene exposure: An overview of monitoring methods and their findings’, Chemico-Biological Interactions, 184(1–2), pp. 58–66. doi:10.1016/j.cbi.2009.12.030.

WHO (1985) Toluene, International Programme on Chemical Safety, World Health Organization & WHO Task Group on Environmental Health Criteria for Toluene.

WHO (2021) WHO human health risk assessment toolkit: chemical hazards. 2nd edn, IPCS harmonization project document. 2nd edn.

Bahasa Abstract

Pekerja pada unit produksi minyak dan gas bumi berisiko memberi pajanan terpajan bahaya kimia. Salah satu bahan dari minyak bumi adalah volatile organic compounds (VOC), dengan contoh bahan yang terkenal akan toksisitasnya adalah benzene, toluene dan xylene. Penelitian ini bertujuan untuk menganalisis risiko kesehatan terkait pajanan benzene, toluene dan xylene pekerja kilang minyak di PT. X. Penelitian akan menganalisis data pajanan personal rute inhalasi dari bahan kimia benzene, toluene dan xylene menggunakan metode Chemical Health Risk Assessment (CHRA) dari Department of Safety and Health, Malaysia. Hasil penelitian menunjukkan tingkat risiko dari benzene sangat tinggi, sedangkan tingkat risiko dari toluene dan xylene berada pada tingkat sedang. Pajanan tertinggi dari benzene, toluene dan xylene berada pada unit distilasi. Berdasarkan hasil penelitian, diperlukan pengendalian yang tepat untuk mengatasi pajanan benzene, toluene dan xylene, Salah satu pengendalian yang dapat dilakukan adalah meningkatkan sistem ventilasi dan memperketat penggunaan alat pelindung diri.

Kata Kunci: kilang minyak, kajian risiko kesehatan, benzene, toluene, xylene

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